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Discovering Lecithin: A Versatile Natural Ingredient Discovering Lecithin: A Versatile Natural Ingredient
Written by Oriol Viladevall
23.04.2024

Discovering Lecithin: A Versatile Natural Ingredient

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Discovering Lecithin: A Versatile Natural Ingredient

Valentino Levak

Sales & Product Manager

IMPAG AG

+41 43 499 25 28E-mail LinkedIn

Lecithin is a natural ingredient used as an emulsifier in a variety of commercial products. Derived from fractions of sunflower, soybean and rapeseed oils, lecithin has particular physico-chemical characteristics that make it essential for the creation of stable and homogeneous emulsions.

Sunflower and Rapeseed are the most popular sources for lecithin

Lecithin is a naturally occurring ingredient used as emulsifier, defined by the European additives legislation as E-322, as member of the family of emulsifier additives. Commercially, it is obtained from the oil fraction of sunflower, soybean and rapeseed, which entail some physico-chemical particularities.

Historically, soy has been the main source for lecithin, but at the beginning of the 1990s, due to the allergic potential of soy alternatives based on sunflower and rapeseed became popular. 

Chemically, we associate lecithin with phospholipids, chemical compounds that are determined by their insolubility in acetone, so its content in technical data sheets the term “IA” is used and stands for “Acetone-Insoluble phosphatides”.

 

Offering a wide variety of applications

Lecithin is defined as triglycerides linked to phospholipids. The most relevant in this family of phospholipids is phosphatidylcholine (PC), the main phosphatide which is represented by 70 % in egg, by 22 % in soy and by 37 % in rapeseed.

This variety means that under the lecithin umbrella we have products with very different properties which are suitable for a wide variety of applications ranging from chocolate, bakery and powder dispersion to cosmetics, pharmaceuticals and technical applications such as paints.

Emulsions are classified by HLB (Hydrophilic Lipophilic Balance, a scale from 1 to 20), which gives a value for the degree of presence of oil or water in the emulsion, with low values being very lipophilic and greater than 10 being very hydrophilic.

 

 

The structure of lecithin

Physically, lecithin is a phospholipid consisting of:

  • Hydrophobic part formed by fatty acid chains.
  • Hydrophilic part formed by the choline and the phosphate group.

 

 

Lecithin’s are commercially available in 3 different formats:

 

1.    Fluid lecithin:


Liquid or fluid lecithin (60% phospholipids):

This is a product with high viscosity, emulsifying and fluidizing properties, essential in the manufacture of chocolate (HLB between 3-4).


Liquid lecithin variant, partially hydrolysed:

In this case, and only as an exception, the legislation allows a minimum phospholipid content of 56% instead of 60%. Its use is more hydrophilic and one of the applications is to avoid splattering when using margarine for frying. (HLB 9)

 

2.    Powder or deoiled lecithin:


It is so called because it is obtained by increasing the purity of IA up to 97% by eliminating the fat. It is a product used in different applications due to its easy handling (HLB 4-5).

 

3.    Lecithin specialties:


Powder variant:

Application of liquid lecithin on a powder carrier (wheat flour, soya flour). IA content between 12-15 %.

 

Liquid variant:

Mix of two liquid products and in the conversion to powder form by drying (mainly spray drying). An Example would be a combination of whey and lecithin. IA content between 25-30%.

 

Learn more

 

Lecithin in Instantizing technology

Lecithin has the ability to improve the dispersion of powdered products. It has this function because it possesses two essential factors:

  • It shortens the sinking time of the powder in the liquid.
  • It stabilizes the emulsion, through a fine and stable dispersion.

 

The following product types profit from the addition of Lecithin:

  • Hydrophobic powders such as whole milk, cocoa powder or some milk formulas for infants.
  • Hydrophilic powders such as caseinates, protein drinks, some lacto-serum, which are difficult to disperse due to their particle size.

 

The two essential factors of lecithin in this application play a key role in improving its ability to disperse in the liquid but also once dispersed, to stabilize it. Factors such as temperature can help in dispersing but not in keeping it stable.

Technologically, there are different Lecithination methods depending on the product to be solubilized, but basically it is a matter of incorporating the lecithin in small microparticles on the powdered product (ideally in the form of a spray) and mixing it correctly to achieve a good homogenization and avoid the formation of lumps. 

In the industry there are processes adapted to this application, the Lödige technology being one of the most advanced. However, this method can have difficulties due to the high viscosity of lecithin, so it is necessary to heat it to temperatures close to 60-70 ºC or to use lecithin "diluted" in oils. Other systems use lecithin in powder form actively mixed with the product to be instantized. The latter method is easier but the results are less reliable.

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